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- W2328852860 abstract "Carbon-13 NMR data are reported and discussed for 32 simple tetraorganotins RnSnR′4-n (n = 0–4) in which the tin atom is four-coordinate. It is found that the value of 1J(SnC) in compounds R4Sn depends on the effective nuclear charge at tin; in mixed organotins Bent's postulate is apparently verified, and in a number of cases coupling constants can again be correlated with Taft σ★ constants for the alkyl groups. The values of 1J(SnCH2) in benzyltin compounds are clearly anomalous. Long-range tin—carbon coupling constants are discussed. The chemical shifts of the carbons in methyl groups bound to tin provide a second useful probe for estimating the electron-withdrawing or electron-releasing power of alkyl and other groups bound to the tin atom." @default.
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- W2328852860 date "1976-11-01" @default.
- W2328852860 modified "2023-09-23" @default.
- W2328852860 title "Fourier transform NMR investigations on organotin compounds" @default.
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- W2328852860 doi "https://doi.org/10.1016/s0022-328x(00)80765-2" @default.
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