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• W2328853919 startingPage "5473" @default.
• W2328853919 abstract "The solid state structures of the cobalt–alkyne complexes (η5-C5H5)(PPh3)Co{η2-(R3Si)C≡C(SO2Ar)} (3-TMS, R = Me, Ar = C6H5; 3-TIPS, R = CH(CH3)2, Ar = p-C6H4CH3) and the noncoordinated alkyne (Me3Si)C≡C(SO2Ph) (6-TMS) have been characterized by X-ray crystallography and, in the case of 3-TMS, 6-TMS, and (η5-C5H5)Co{η2-(Me3Si)C≡C(SO2Ph)} (5-TMS-calc), by B97D/Def2-TZVPP computational analysis. The phosphine-dissociated complex 5-TMS-calc is determined to be a ground state singlet. Analysis of bond angle and distance metrics, calculated NMR chemical shift data, and molecular orbital analysis provide strong evidence for a four-electron-donor alkyne ligand in 5-TMS-calc. The degree of asymmetry in metal–alkyne bonding, as defined by the Gladysz alkyne-slippage parameter, is dramatically reduced in 5-TMS-calc relative to that in the precursor complex 3-TMS-calc." @default.
• W2328853919 created "2016-06-24" @default.
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• W2328853919 date "2013-09-13" @default.
• W2328853919 modified "2023-10-18" @default.
• W2328853919 title "Structural Characterization of (C₅H₅)Co(PPh₃)(η²-alkyne) and (C₅H₅)Co(η²-alkyne) Complexes of Highly Polarized Alkynes" @default.
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• W2328853919 doi "https://doi.org/10.1021/om400749g" @default.
• W2328853919 hasPublicationYear "2013" @default.
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