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- W2328880991 abstract "Four new boron-dipyrromethenes (BODIPYs) containing dipyrromethanyl substituents at 3,5-positions, bis(3,5-dipyrromethanyl) BODIPYs 5-8, were synthesized by treating their corresponding 3,5-diformyl BODIPYs 1-4 with excess pyrrole under mild acid catalyzed reaction conditions. The compounds 5-8 are stable and freely soluble in common organic solvents. One-dimensional, two-dimensional NMR, high resolution mass spectrometry (HRMS), absorption, fluorescence, and electrochemical techniques were used to characterize the compounds. The spectral and electrochemical studies indicated that dipyrromethanyl groups at 3,5-positions of BODIPY are less electron deficient compared to formyl groups at the same positions. The anion binding studies indicated that bis(3,5-dipyrromethanyl) BODIPY compounds containing four pyrrole NH groups showed preferential binding with F(-) ion over other anions, as confirmed by using NMR, fluorescence, and electrochemical studies." @default.
- W2328880991 created "2016-06-24" @default.
- W2328880991 creator A5002660612 @default.
- W2328880991 creator A5066599736 @default.
- W2328880991 date "2012-03-20" @default.
- W2328880991 modified "2023-10-14" @default.
- W2328880991 title "Synthesis, Spectral, Electrochemical, and Anion Binding Properties of 3,5-Bis(Dipyrromethanyl) Boron-Dipyrromethenes" @default.
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- W2328880991 doi "https://doi.org/10.1021/ic202758r" @default.
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