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• W2328964834 abstract "Dinuclear Ni complexes supported by naphthyridine-diimine (NDI) ligands catalyze the reductive cyclopropanation of alkenes with CH2 Cl2 as the methylene source. The use of mild terminal reductants (Zn or Et2 Zn) confers significant functional-group tolerance, and the catalyst accommodates structurally and electronically diverse alkenes. Mononickel catalysts bearing related N chelates afford comparatively low cyclopropane yields (≤20 %). These results constitute an entry into catalytic carbene transformations from oxidized methylene precursors." @default.
• W2328964834 created "2016-06-24" @default.
• W2328964834 creator A5017105062 @default.
• W2328964834 creator A5060118311 @default.
• W2328964834 date "2016-01-28" @default.
• W2328964834 modified "2023-10-17" @default.
• W2328964834 title "Reductive Cyclopropanations Catalyzed by Dinuclear Nickel Complexes" @default.
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• W2328964834 doi "https://doi.org/10.1002/anie.201511271" @default.
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