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• W2329092746 endingPage "7052" @default.
• W2329092746 startingPage "7043" @default.
• W2329092746 abstract "Highly efficient alkene hydrogenations were developed using NO-functionalized hydrido dinitrosyl rhenium catalysts of the type [ReH(PR3)2(NO)(NO(LA))][Z] (2, LA = B(C6F5)3; 3, LA = [Et]+, Z = [B(C6F5)4]−; 4, LA = [SiEt3]+, Z = [HB(C6F5)3]−; R = iPr a, Cy b). Lewis acid attachment to the NO ligand was found to facilitate bending at the NOLA atom and concomitantly to open up a vacant site at the rhenium center. According to DFT calculations, the ability to bend follows the order 4 > 3 > 2, which did not match with the order of increasing hydrogenation activities: 3 > 4 > 2. The main factor spoiling catalytic performance was catalyst deactivation by detachment of the LA group occurring during the catalytic reaction course, which was found to go along with the decrease in order of DFT-calculated strengths of the ONO–LA bonds. LA detachment from the ONO atom could at least partly be prevented by LA addition as cocatalysts, which led to an extraordinary boost of the hydrogenation activities. For instance the “1/hydrosilane/B(C6F5)3” (1:5:5) system exhibited the highest performance, with TOFs up to 1.2 × 105 h–1 (1-hexene, 1-octene, cyclooctene, cyclohexene). The cocatalyst [Et3O][B(C6F5)4] showed the smallest effect, presumably due to the strong Lewis acidic character of the reagent causing side-reactions before reacting with 1a,b. The catalytic reaction course crucially involves not only reversible bending at the NOLA atom but also loss of a PR3 ligand, forming 16e or 14e monohydride reactive intermediates, which drive an Osborn-type hydrogenation cycle with olefin before H2 addition." @default.
• W2329092746 created "2016-06-24" @default.
• W2329092746 creator A5001794559 @default.
• W2329092746 creator A5001975504 @default.
• W2329092746 creator A5011276051 @default.
• W2329092746 creator A5041097915 @default.
• W2329092746 creator A5048074828 @default.
• W2329092746 creator A5062932399 @default.
• W2329092746 date "2013-11-04" @default.
• W2329092746 modified "2023-09-25" @default.
• W2329092746 title "Efficient Lewis Acid Promoted Alkene Hydrogenations Using Dinitrosyl Rhenium(−I) Hydride Catalysts" @default.
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• W2329092746 doi "https://doi.org/10.1021/om400733u" @default.

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