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- W2329129718 endingPage "5341" @default.
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- W2329129718 abstract "Iodine and the pincer complex [Pd(O,N,C-L)I], where L is the monoanionic ligand resulting from deprotonation of the acetyl group of the dimethylmonoketal of 2,6-diacetylpyridine, are in equilibrium at low temperatures with the palladium(IV) complex [Pd(O,N,C-L)I3], which can be isolated at −40 °C and characterized by 1H NMR spectroscopy and X-ray diffraction studies, in spite of its great instability. When the same reaction is carried out at room temperature, a quantitative reductive elimination process occurs, giving L–I, which in the presence of water affords L′–I, resulting from hydrolysis of L–I." @default.
- W2329129718 created "2016-06-24" @default.
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- W2329129718 creator A5077311329 @default.
- W2329129718 date "2011-05-25" @default.
- W2329129718 modified "2023-09-24" @default.
- W2329129718 title "Synthesis, Isolation, and Characterization of an Organometallic Triiodopalladium(IV) Complex. Quantitative and Regioselective Synthesis of Two C–I Reductive Elimination Products" @default.
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- W2329129718 doi "https://doi.org/10.1021/ic2006869" @default.
- W2329129718 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21612258" @default.
- W2329129718 hasPublicationYear "2011" @default.
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