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• W2329339642 startingPage "6862" @default.
• W2329339642 abstract "We propose a method to calculate the ideal shear strength τ of two surfaces in contact by ab initio calculations. This quantity and the work of adhesion γ are the interfacial parameters usually derived from tip-based friction force measurements. We consider diamond interfaces and quantitatively evaluate the effects of surface orientation and passivation. We find that in the case of fully passivated interfaces, γ is not affected by the orientation and the alignment of the surfaces in contact. On the contrary, τ does show a dependence on the atomic-scale roughness of the interface. The surface termination has a major impact on the tribological properties of diamond. The presence of dangling bonds, even at concentrations low enough to prevent the formation of interfacial C–C bonds, causes an increase in the resistance to sliding by 2 orders of magnitude with respect to the fully hydrogenated case. We discuss our findings in relation to experimental observations." @default.
• W2329339642 created "2016-06-24" @default.
• W2329339642 creator A5064500027 @default.
• W2329339642 creator A5066285491 @default.
• W2329339642 date "2011-05-05" @default.
• W2329339642 modified "2023-10-11" @default.
• W2329339642 title "Ab Initio Calculation of the Adhesion and Ideal Shear Strength of Planar Diamond Interfaces with Different Atomic Structure and Hydrogen Coverage" @default.
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• W2329339642 doi "https://doi.org/10.1021/la200783a" @default.
• W2329339642 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21545120" @default.
• W2329339642 hasPublicationYear "2011" @default.
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