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• W2329545619 endingPage "22959" @default.
• W2329545619 startingPage "22954" @default.
• W2329545619 abstract "Oxidation of toluene was catalyzed by bare and TiO2-covered NiO-Ni(OH)2 nanoparticles under humid air. For deposition of TiO2, atomic layer deposition was used. Bare NiO-Ni(OH)2 showed a significantly high activity for toluene oxidation. When TiO2 islands were deposited on NiO, formation of CO2 as a result of total oxidation of toluene was completely suppressed at 180 °C, even though the substrate surface was only partially covered by TiO2. We suggest that TiO2 islands preferentially blocked the active sites for total oxidation of toluene under our experimental conditions. On the basis of the X-ray photoelectron spectroscopy data, catalyst surfaces consisted of NiO and Ni(OH)2, and NiO was active for toluene total oxidation, whereas Ni(OH)2 was not. Studies of change in the activity of a heterogeneous catalyst upon preferential decoration of specific surface sites can shed light on the structures and properties of catalytically active sites." @default.
• W2329545619 created "2016-06-24" @default.
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• W2329545619 date "2011-11-03" @default.
• W2329545619 modified "2023-09-24" @default.
• W2329545619 title "Oxidation of Toluene on Bare and TiO2-Covered NiO-Ni(OH)2 Nanoparticles" @default.
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• W2329545619 doi "https://doi.org/10.1021/jp2065997" @default.
• W2329545619 hasPublicationYear "2011" @default.
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