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- W2329669467 abstract "Report herein is an integrated catalytic process for conversion and upgrading of biomass feedstocks into 5,5′-dihydroxymethyl furoin (DHMF), through self-coupling of 5-hydroxymethyl furfural (HMF) via organocatalysis, and subsequently into n-C12H26 alkane fuel via metal–acid tandem catalysis. The first step of the process involves semicontinuous organocatalytic conversion of biomass (fructose, in particular) to the high-purity HMF. N-Heterocyclic carbenes (NHCs) are found to catalyze glucose-to-fructose isomerization, and the relatively inexpensive thiazolium chloride [TM]Cl, a Vitamin B1 analog, catalyzes fructose dehydration to HMF of good purity (>99% by HPLC), achieving a constant HMF yield of 72% over 10 semicontinuous extraction batch runs. Crystallization of the crude HMF from toluene yields the spectroscopically and analytically pure HMF as needle crystals. The second step of the process is the NHC-catalyzed coupling of C6 HMF produced by the semicontinuous process to C12 DHMF; the most effective ..." @default.
- W2329669467 created "2016-06-24" @default.
- W2329669467 creator A5018137652 @default.
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- W2329669467 date "2014-03-31" @default.
- W2329669467 modified "2023-10-17" @default.
- W2329669467 title "Integrated Catalytic Process for Biomass Conversion and Upgrading to C<sub>12</sub> Furoin and Alkane Fuel" @default.
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- W2329669467 doi "https://doi.org/10.1021/cs500058p" @default.
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