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- W2329800524 abstract "Herein we report the synthesis of a chiral imidazolium salt derived from trans-l-hydroxyproline and its applications as a catalyst for the asymmetric aldol reaction. By performing the aldol reaction in [Bmim]NTf2 as a solvent, we report excellent isolated yields of the aldol product (up to 99%), as well as modest to excellent selectivities (dr superior to 99:1. ee up to 89%). Mechanistic insights and the origins of the selectivity of the aldol reaction are discussed on the basis of the results obtained with two catalytic imidazolium salts having different H-bonding potential." @default.
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- W2329800524 date "2012-05-17" @default.
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- W2329800524 title "Asymmetric Aldol Reaction Catalyzed by the Anion of an Ionic Liquid" @default.
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- W2329800524 doi "https://doi.org/10.1021/jo300737u" @default.
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