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• W2329878584 abstract "Abstract The new compound [Mn 2 (bipy) 4 SbS 4 ](ClO 4 ) was prepared by a new synthetic route for the preparation of thioantimonates(V) that can be used even at room temperature. Mixing aqueous solutions of [Mn(bipy) 3 ](ClO 4 ) 2 and Na 3 SbS 4 · 9H 2 O leads to immediate crystallization of the pure compound. In the structure an SbS 4 3– anion acts as a tetradentate bridge connecting two Mn 2+ cations of [Mn(bipy) 3 ] 2+ complexes (bipy = 2,2′-bipyridine). The compound features a hitherto unknown [Mn 2 (bipy) 4 SbS 4 ] + cation. Bipy ligands of adjacent cations are arranged parallel to each other leading to weak off-center parallel π - π interactions stabilizing the crystals. Magnetic measurements indicate weak antiferromagnetic exchange interactions between the Mn 2+ centers." @default.
• W2329878584 created "2016-06-24" @default.
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• W2329878584 date "2016-03-08" @default.
• W2329878584 modified "2023-09-25" @default.
• W2329878584 title "Room temperature synthesis, crystal structure and selected properties of the new compound [Mn₂(bipy)₄SbS₄](ClO₄)" @default.
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• W2329878584 doi "https://doi.org/10.1515/znb-2015-0205" @default.
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