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- W2329884080 abstract "Two monomeric gallium−nitrogen compounds, Et2GaNH[C6H2(2,4,6-t-Bu)3] and EtGa{NH[C6H2(2,4,6-t-Bu)3]}2, have been prepared by metathetical reactions between either Et2GaCl or EtGaCl2, as appropriate, and LiNH[C6H2(2,4,6-t-Bu)3] and have been characterized fully. Cryoscopic molecular weight studies demonstrated both compounds to be monomeric in benzene solution, whereas an X-ray structural study of the latter identified a monomer. The compound Et2GaNH[C6H2(2,4,6-t-Bu)3] decomposes at room temperature to form a new metallacyclic derivative GaEt3, and H2N[C6H2(2,4,6-t-Bu)3]. A 1H NMR spectral study and an X-ray structural study were used to elucidate its structure. The compound EtGa{NH[C6H2(2,4,6-t-Bu)3]}2 does not decompose to the metallacycle, but it reacts readily with GaEt3 to form Et2GaNH[C6H2(2,4,6-t-Bu)3]." @default.
- W2329884080 created "2016-06-24" @default.
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- W2329884080 date "1999-06-01" @default.
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- W2329884080 title "Monomeric Organogallium−Nitrogen Compounds. Chemistry of Et<sub>2</sub>GaNH[C<sub>6</sub>H<sub>2</sub>(2,4,6-t-Bu)<sub>3</sub>] with Decomposition to the Metallacycle {EtGaNH[C<sub>6</sub>H<sub>2</sub>(4,6-t-Bu)<sub>2</sub>CMe<sub>2</sub>CH<sub>2</sub>-2]}<sub>2</sub> and of EtGa{NH[C<sub>6</sub>H<sub>2</sub>(2,4,6-t-Bu)<sub>3</sub>]}<sub>2</sub>" @default.
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- W2329884080 doi "https://doi.org/10.1021/om990136+" @default.
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