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• W2329920475 abstract "Poly(N-isopropylacrylamide-co-N,N′-dimethylaminoethyl methacrylate sulfate) [P(NIPAM-co-DMAEMASA)] was prepared from N-isopropylacrylamide (NIPAM) and N,N-dimethylaminoethyl methacrylate sulfate (DMAEMASA) monomers, and its properties were compared with those of poly(N-isopropylacrylamide-co-N,N′-dimethylaminoethyl methacrylate) [P(NIPAM-co-DMAEMA)]. The copolymers were characterized by swelling measurements in distilled water (10−40 °C) and buffer solutions (I = 0.1 M, pH = 2.2−10.0), FTIR, DSC, and SEM methods. The ESV’s of the NIPAM-DMAEMASA copolymers in distilled water were 5 times higher than those of P(NIPAM-co-DMAEMA); they decreased with an increase in comonomer (DMAEMASA/DMAEMA) content for both copolymers. While NIPAM-DMAEMASA copolymers did not display any phase transition with temperature, the LCST of the NIPAM-DMAEMA copolymer was determined as 20 °C. Both copolymers displayed a phase transition at pH = 5.0, but the pH of the phase transition for NIPAM-DMAEMA gels shifted to 7.0 with increased DMAEMA content. Glass transition temperatures of NIPAM copolymers did not change with the type and content of comonomer." @default.
• W2329920475 created "2016-06-24" @default.
• W2329920475 creator A5007542268 @default.
• W2329920475 creator A5054721346 @default.
• W2329920475 date "2010-11-02" @default.
• W2329920475 modified "2023-10-17" @default.
• W2329920475 title "Synthesis and Characterization of Novel Poly(<i>N</i>-isopropylacrylamide-co-<i>N</i>,<i>N</i>′-dimethylaminoethyl methacrylate sulfate) Hydrogels" @default.
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• W2329920475 doi "https://doi.org/10.1021/ie101577r" @default.
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