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• W2329927558 abstract "This paper reports the results of crystallography and crystal chemistry investigation of the (Ba 1− x Sr x )Y 2 CuO 5 (“green phase”) solid solution series by X-ray powder diffraction (XPD) and neutron powder diffraction techniques. The single phase regions for (Ba 1− x Sr x )Y 2 CuO 5 were determined to be 0⩽ x ⩽0.3 for samples prepared at 810 °C in 100 Pa p O2 , and 0⩽ x ⩽0.7 for samples prepared at 930 °C in air. All single phase (Ba 1− x Sr x )Y 2 CuO 5 samples are isostructural to BaY 2 CuO 5 and can be indexed using an orthorhombic cell with the space group Pnma. Lattice parameters, a , b , c and the cell volume, V , of the (Ba 1− x Sr x )Y 2 CuO 5 members decrease linearly with increasing Sr substitution ( x ) on the Ba site. The general structure of (Ba 1− x Sr x )Y 2 CuO 5 can be considered as having a three-dimensional interconnected network of [YO 7 ],[(Ba,Sr)O 11 ], and [CuO 5 ] polyhedra. The copper ions are located inside distorted [CuO 5 ] “square” pyramids. These pyramids are connected by the [Y 2 O 11 ] groups that are formed from two monocapped [YO 7 ] trigonal prisms sharing a triangular face. The Ba 2+ ions are found to reside in distorted 11-fold coordinated cages. The oxygen sites are essentially fully occupied. XPD reference patterns of two members of the series, (Ba 0.3 Sr 0.7 )Y 2 CuO 5 and (Ba 0.7 Sr 0.3 )Y 2 CuO 5 , were prepared for inclusion in the powder diffraction file." @default.
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• W2329927558 date "2006-09-01" @default.
• W2329927558 modified "2023-09-25" @default.
• W2329927558 title "X-ray and neutron powder diffraction studies of (Ba1−xSrx)Y2CuO5" @default.
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• W2329927558 doi "https://doi.org/10.1154/1.2217029" @default.
• W2329927558 hasPublicationYear "2006" @default.
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