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- W2329982813 abstract "Structure–reactivity relationship (SRR) studies to understand the effect of N-α substitution toward electroactive poly(pyrrole) film formation have carefully been performed. To conduct these SRR studies, a selected chemical library of 21 different N-substituted pyrrole derivatives has been developed using the key well-known Clauson–Kass synthetic reaction from corresponding amine precursors. While investigating electropolymerization features of these novel N-substituted pyrroles, we observed that the steric factor due to α-substitution, one among other factors, plays the most significant role in preventing electropolymerization of these oxidizable chemical species. Interestingly, even a sterically small chemical group like a CH3 one present at α-position is large enough to prevent monomer electropolymerization. Density functional theory calculations were carried out to analyze the polymerization of substituted pyrrole molecules and to understand the effect of N-substituents on electropolymerization toward the formation of functional conductive film. This systematic study paves the way to effectively design the right N-substitution for the obtainment of corresponding modified functional electrodes for further related applications." @default.
- W2329982813 created "2016-06-24" @default.
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- W2329982813 date "2014-01-28" @default.
- W2329982813 modified "2023-10-16" @default.
- W2329982813 title "Effect of N-α Substitution on the Electropolymerization of N-Substituted Pyrroles: Structure–Reactivity Relationship Studies" @default.
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- W2329982813 doi "https://doi.org/10.1021/jp411098y" @default.
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