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- W2330004959 abstract "We report the formation and systematic struc-tural characterization of a new AB(6) polymorph with the body-centered cubic (bcc) symmetry in binary nanocrystal superlattices (BNSLs). The bcc-AB(6) phase, lacking any atomic analogue, is isomorphic to certain alkali-metal intercalation compounds of fullerene C(60) (e.g., K(6)C(60)). On the basis of the space-filling principle, we further tailor the relative phase stability of the two AB(6) polymorphs-CaB(6) and bcc-AB(6)-from coexistence to phase-pure bcc-AB(6), highlighting the entropic effect as the main driving-force of the self-organization of BNSLs. We also discuss the implication of surface topology studies and the observation of twinning and preferential orientation in bcc-AB(6) on the growth mechanism of BNSLs. Furthermore, the connection between the bcc-AB(6) phase and the (3(2).4.3.4) Archimedean tiling shows the promise of further exploration on the structural diversity (both periodic and aperiodic) in this emerging class of metamaterials. The identification and the ability to tune the relative phase stability of polymorphic structures provide a unique opportunity to engineer the interparticle coupling through controlled clustering and/or interconnectivity of sublattice in BNSLs with identical stoichiometry." @default.
- W2330004959 created "2016-06-24" @default.
- W2330004959 creator A5029603338 @default.
- W2330004959 creator A5082857859 @default.
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- W2330004959 date "2011-02-03" @default.
- W2330004959 modified "2023-10-17" @default.
- W2330004959 title "Polymorphism in Self-Assembled AB<sub>6</sub> Binary Nanocrystal Superlattices" @default.
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- W2330004959 doi "https://doi.org/10.1021/ja108708v" @default.
- W2330004959 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21291278" @default.
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