Matches in SemOpenAlex for { <https://semopenalex.org/work/W2330021311> ?p ?o ?g. }
- W2330021311 endingPage "2769" @default.
- W2330021311 startingPage "2760" @default.
- W2330021311 abstract "The reaction mechanism of nitric oxide (NO) reduction by excess electrons on TiO2 nanoparticles (eTiO2–) has been studied under anaerobic conditions. TiO2 was loaded with 10–130 electrons per particle using γ-irradiation of acidic TiO2 colloid solutions containing 2-propanol. The study is based on time-resolved kinetics and reactants and products analysis. The reduction of NO by eTiO2– is interpreted in terms of competition between a reaction path leading to formation of NH3 and a path leading to N2O and N2. The proposed mechanism involves consecutive one-electron transfers of NO, and its reduction intermediates HNO, NH2O•, and NH2OH. The results show that eTiO2– does not reduce N2O and N2. Second-order rate constants of eTiO2– reactions with NO (740 ± 30 M–1 s–1) and NH2OH (270 ± 30 M–1 s–1) have been determined employing the rapid-mixing stopped-flow technique and that with HNO (>1.3 × 106 M–1 s–1) was derived from fitting the kinetic traces to the suggested reaction mechanism, which is discussed in detail." @default.
- W2330021311 created "2016-06-24" @default.
- W2330021311 creator A5019702122 @default.
- W2330021311 creator A5021740808 @default.
- W2330021311 creator A5032816899 @default.
- W2330021311 creator A5033548896 @default.
- W2330021311 date "2015-03-16" @default.
- W2330021311 modified "2023-09-28" @default.
- W2330021311 title "Nitric Oxide Reduction to Ammonia by TiO<sub>2</sub> Electrons in Colloid Solution via Consecutive One-Electron Transfer Steps" @default.
- W2330021311 cites W128722722 @default.
- W2330021311 cites W1552748132 @default.
- W2330021311 cites W1963485384 @default.
- W2330021311 cites W1963546413 @default.
- W2330021311 cites W1963905651 @default.
- W2330021311 cites W1964058023 @default.
- W2330021311 cites W1968306497 @default.
- W2330021311 cites W1973140371 @default.
- W2330021311 cites W1986452585 @default.
- W2330021311 cites W1986802380 @default.
- W2330021311 cites W1991436728 @default.
- W2330021311 cites W1992109465 @default.
- W2330021311 cites W1994390546 @default.
- W2330021311 cites W1997654816 @default.
- W2330021311 cites W2001499501 @default.
- W2330021311 cites W2004079715 @default.
- W2330021311 cites W2006154174 @default.
- W2330021311 cites W2007773843 @default.
- W2330021311 cites W2014710896 @default.
- W2330021311 cites W2026048374 @default.
- W2330021311 cites W2027395781 @default.
- W2330021311 cites W2027998872 @default.
- W2330021311 cites W2030150400 @default.
- W2330021311 cites W2034382046 @default.
- W2330021311 cites W2041698310 @default.
- W2330021311 cites W2048749550 @default.
- W2330021311 cites W2049294646 @default.
- W2330021311 cites W2060108196 @default.
- W2330021311 cites W2060188807 @default.
- W2330021311 cites W2073551123 @default.
- W2330021311 cites W2074245012 @default.
- W2330021311 cites W2084441023 @default.
- W2330021311 cites W2089102198 @default.
- W2330021311 cites W2110540540 @default.
- W2330021311 cites W2118258213 @default.
- W2330021311 cites W2312954251 @default.
- W2330021311 cites W2330835028 @default.
- W2330021311 cites W2543016147 @default.
- W2330021311 cites W2950799351 @default.
- W2330021311 doi "https://doi.org/10.1021/jp5102863" @default.
- W2330021311 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25730520" @default.
- W2330021311 hasPublicationYear "2015" @default.
- W2330021311 type Work @default.
- W2330021311 sameAs 2330021311 @default.
- W2330021311 citedByCount "11" @default.
- W2330021311 countsByYear W23300213112015 @default.
- W2330021311 countsByYear W23300213112016 @default.
- W2330021311 countsByYear W23300213112017 @default.
- W2330021311 countsByYear W23300213112018 @default.
- W2330021311 countsByYear W23300213112020 @default.
- W2330021311 countsByYear W23300213112021 @default.
- W2330021311 crossrefType "journal-article" @default.
- W2330021311 hasAuthorship W2330021311A5019702122 @default.
- W2330021311 hasAuthorship W2330021311A5021740808 @default.
- W2330021311 hasAuthorship W2330021311A5032816899 @default.
- W2330021311 hasAuthorship W2330021311A5033548896 @default.
- W2330021311 hasConcept C113196181 @default.
- W2330021311 hasConcept C121332964 @default.
- W2330021311 hasConcept C123669783 @default.
- W2330021311 hasConcept C147120987 @default.
- W2330021311 hasConcept C147789679 @default.
- W2330021311 hasConcept C148898269 @default.
- W2330021311 hasConcept C161790260 @default.
- W2330021311 hasConcept C175113610 @default.
- W2330021311 hasConcept C178790620 @default.
- W2330021311 hasConcept C179104552 @default.
- W2330021311 hasConcept C184651966 @default.
- W2330021311 hasConcept C185592680 @default.
- W2330021311 hasConcept C2776382133 @default.
- W2330021311 hasConcept C2779851234 @default.
- W2330021311 hasConcept C42296456 @default.
- W2330021311 hasConcept C59789625 @default.
- W2330021311 hasConcept C62520636 @default.
- W2330021311 hasConcept C65024703 @default.
- W2330021311 hasConcept C66887884 @default.
- W2330021311 hasConcept C75473681 @default.
- W2330021311 hasConcept C93391505 @default.
- W2330021311 hasConceptScore W2330021311C113196181 @default.
- W2330021311 hasConceptScore W2330021311C121332964 @default.
- W2330021311 hasConceptScore W2330021311C123669783 @default.
- W2330021311 hasConceptScore W2330021311C147120987 @default.
- W2330021311 hasConceptScore W2330021311C147789679 @default.
- W2330021311 hasConceptScore W2330021311C148898269 @default.
- W2330021311 hasConceptScore W2330021311C161790260 @default.
- W2330021311 hasConceptScore W2330021311C175113610 @default.
- W2330021311 hasConceptScore W2330021311C178790620 @default.
- W2330021311 hasConceptScore W2330021311C179104552 @default.
- W2330021311 hasConceptScore W2330021311C184651966 @default.
- W2330021311 hasConceptScore W2330021311C185592680 @default.