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• W2330111579 abstract "The kinetics of the reaction of limonene (C10H16) with F2 has been studied using a low pressure (P = 1 Torr) and a high pressure turbulent (P = 100 Torr) flow reactor coupled with an electron impact ionization and chemical ionization mass spectrometers, respectively: F2 + Limonene → products (1). The rate constant of the title reaction was determined under pseudo-first-order conditions by monitoring either limonene or F2 decay in excess of F2 or C10H16, respectively. The reaction rate constant, k1 = (1.15 ± 0.25) × 10–12 exp(160 ± 70)/T) was determined over the temperature range 278–360 K, independent of pressure between 1 (He) and 100 (N2) Torr. F atom and HF were found to be formed in reaction 1, with the yields of 0.60 ± 0.13 and 0.39 ± 0.09, respectively, independent of temperature in the range 296–355 K." @default.
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• W2330111579 date "2014-10-28" @default.
• W2330111579 modified "2023-10-17" @default.
• W2330111579 title "Reaction of Limonene with F₂: Rate Coefficient and Products" @default.
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• W2330111579 doi "https://doi.org/10.1021/jp509498a" @default.
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