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- W2330231495 endingPage "1102" @default.
- W2330231495 startingPage "1098" @default.
- W2330231495 abstract "Using a grafting-through strategy, brush polymers containing semiconducting polyene backbones were efficiently synthesized by cyclopolymerization for the first time. Macromonomers containing poly(l-lactide) and poly(ε-caprolactone), prepared by living ring-opening polymerization, were polymerized using the Grubbs-Hoveyda catalyst to produce high molecular weight (>0.5 M Da) brush polymers. The brush polymers underwent a unique coil-to-rod transition during the aging of the polymer solution, and this conformational change was supported by UV-vis and size-exclusion chromatography (SEC)-viscometry analysis. In addition, the extended conformation of single chains of the brush polymers could be visualized by atomic force microscopy." @default.
- W2330231495 created "2016-06-24" @default.
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- W2330231495 date "2012-08-15" @default.
- W2330231495 modified "2023-09-23" @default.
- W2330231495 title "Brush Polymers Containing Semiconducting Polyene Backbones: Graft-Through Synthesis via Cyclopolymerization and Conformational Analysis on the Coil-to-Rod Transition" @default.
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- W2330231495 doi "https://doi.org/10.1021/mz3002897" @default.
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