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- W2330250997 abstract "The dissociation constant of m-nitrophenol in 50 wt percent methanol-water as solvent has been determined at 25, 30, 35, and 40 °C. A spectrophotometric method was used, together with acidity functions for buffer solutions in 50 percent methanol derived from previous emf measurements. Values of the enthalpy and entropy changes on dissociation of the phenol have been calculated. A comparison with corresponding values for the dissociation of m-nitrophenol in aqueous solution affords a measure of the medium effect. The medium effect for m-nitrophenol lies intermediate between that for o-nitrophenol and that for p-nitrophenol." @default.
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- W2330250997 date "1967-01-01" @default.
- W2330250997 modified "2023-10-17" @default.
- W2330250997 title "Dissociation constant of m-nitrophenol in 50 wt percent methanol-water solvent from 25 to 40 C and related medium effects" @default.
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- W2330250997 doi "https://doi.org/10.6028/jres.071a.005" @default.
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