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- W2330308175 abstract "Three isoelectronic analogues of pyrido[2,1-a]isoindole have been found to undergo a facile 1,1-hydroboration with HBMes2 borane, which provides a new and convenient method for the synthesis of B,N-heterocycles 1a–3a in high yields. Compounds 1a–3a can undergo photoelimination upon irradiation at 300 nm, generating heterocycle-fused B,N-naphthalene molecules 1b–3b, which display distinct yellow-green and blue fluorescent colors, respectively. Compound 1a undergoes thermal elimination, producing 1b at 280 °C, while compound 2a only undergoes partial elimination, forming 2b at 320 °C. Compound 3a is thermally stable up to 320 °C." @default.
- W2330308175 created "2016-06-24" @default.
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- W2330308175 date "2016-03-22" @default.
- W2330308175 modified "2023-10-07" @default.
- W2330308175 title "1,1-Hydroboration of Fused Azole–Isoindole Analogues as an Approach for Construction of <i>B</i>,<i>N</i>-Heterocycles and Azole-Fused <i>B</i>,<i>N</i>-Naphthalenes" @default.
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- W2330308175 doi "https://doi.org/10.1021/acs.orglett.6b00485" @default.
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