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- W2330336329 endingPage "4335" @default.
- W2330336329 startingPage "4323" @default.
- W2330336329 abstract "The controlled synthesis of monodisperse, redox-active metallopolymers and their redox properties and functions, including robust electrode derivatization and sensing, remains a challenge. Here a series of polynorbornene homopolymers and block copolymers containing side-chain amidoferrocenyl groups and tetraethylene glycol linkers were prepared via living ring-opening metathesis polymerization initiated by Grubbs’ third-generation catalyst (1). Their molecular weights were determined using MALDI-TOF mass spectra, size exclusion chromatography (SEC), end-group analysis, and the empirical Bard–Anson electrochemical equation. All polymerizations followed a living and controlled manner, and the number of amidoferrocenyl units varied from 5 to 332. These homopolymers and block copolymers were successfully used to prepare modified Pt electrodes that showed excellent stability. The modified Pt electrodes show excellent qualitative sensing of ATP2– anions, in particular those prepared with the block copolymers. The quantitative recognition and titration of [n-Bu4N]2[ATP] was carried out using the CH2Cl2 solution of the homopolymers, showing that two amidoferrocenyl groups of the homopolymers interacted with each ATP2– molecule. This stoichiometry led us to propose the H-bonding modes in the supramolecular polymeric network." @default.
- W2330336329 created "2016-06-24" @default.
- W2330336329 creator A5011221080 @default.
- W2330336329 creator A5033351543 @default.
- W2330336329 creator A5033565884 @default.
- W2330336329 creator A5071668591 @default.
- W2330336329 creator A5072437452 @default.
- W2330336329 creator A5079758666 @default.
- W2330336329 creator A5084906953 @default.
- W2330336329 date "2014-08-05" @default.
- W2330336329 modified "2023-10-16" @default.
- W2330336329 title "Living Ring-Opening Metathesis–Polymerization Synthesis and Redox-Sensing Properties of Norbornene Polymers and Copolymers Containing Ferrocenyl and Tetraethylene Glycol Groups" @default.
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