Matches in SemOpenAlex for { <https://semopenalex.org/work/W2330346876> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W2330346876 endingPage "577" @default.
- W2330346876 startingPage "572" @default.
- W2330346876 abstract "The dehydrogenation of 2, 3-dimethylbutane, 3-methylpentane and methylcyclopentane over Pt-C catalyst was studied at low conversion levels and temperatures ranging from 400 to 480°C, under the hydrogen atmospheric pressure.The dehydrogenated products included all possible alkenes and cycloalkenes possessing the same skeletal structures as raw materials and were approximately in thermodynamic equilibrium at conversions as low as 8%. The compositions of these product mixtures observed at 460°C were: 43% 2, 3-dimethyl-1-butene and 57% 2, 3-dimethyl-2-butene; 9% 3-methyl-1-pentene, 11% 2-ethyl-1-butene, 31% 3-methyl-cis-2-pentene and 49% 3-methyl-trans-2-pentene; 68% 1-methylcyclopentene, 20% 3-methylcyclopentene, 10% 4-methylcyclopentene and 2% methylenecyclopentane in each skeletal hydrocarbons, respectively.At the initial step of the reaction, however, it was shown that 2, 3-dimethyl-1-butene, 3-methyl-1-pentene and 3-methylcyclopentene were formed beyond their thermodynamic equilibrium compositions, respectively.It was found that the rate of the dehydrogenation was influenced by the ratio of hydrogen to hydrocarbon and that in the absence of hydrogen the reaction did not proceed at all. The reaction rate increased with the molar ratios, being constant at the molar ratio of one and above.These results suggested that the hydrogen played an important role on the dehydrogenation mechanism over Pt catalyst used in the present study." @default.
- W2330346876 created "2016-06-24" @default.
- W2330346876 creator A5039429950 @default.
- W2330346876 creator A5058673085 @default.
- W2330346876 creator A5072213437 @default.
- W2330346876 creator A5086501307 @default.
- W2330346876 date "1973-01-01" @default.
- W2330346876 modified "2023-10-15" @default.
- W2330346876 title "Dehydrogenation of C<sub>6</sub>-Saturated Hydrocarbons over Pt Catalyst" @default.
- W2330346876 cites W1560848039 @default.
- W2330346876 cites W3145282968 @default.
- W2330346876 cites W564793319 @default.
- W2330346876 cites W618071006 @default.
- W2330346876 cites W644853776 @default.
- W2330346876 doi "https://doi.org/10.1627/jpi1958.16.572" @default.
- W2330346876 hasPublicationYear "1973" @default.
- W2330346876 type Work @default.
- W2330346876 sameAs 2330346876 @default.
- W2330346876 citedByCount "0" @default.
- W2330346876 crossrefType "journal-article" @default.
- W2330346876 hasAuthorship W2330346876A5039429950 @default.
- W2330346876 hasAuthorship W2330346876A5058673085 @default.
- W2330346876 hasAuthorship W2330346876A5072213437 @default.
- W2330346876 hasAuthorship W2330346876A5086501307 @default.
- W2330346876 hasBestOaLocation W23303468761 @default.
- W2330346876 hasConcept C119889771 @default.
- W2330346876 hasConcept C126661725 @default.
- W2330346876 hasConcept C155647269 @default.
- W2330346876 hasConcept C161790260 @default.
- W2330346876 hasConcept C178790620 @default.
- W2330346876 hasConcept C179104552 @default.
- W2330346876 hasConcept C185592680 @default.
- W2330346876 hasConcept C2776164856 @default.
- W2330346876 hasConcept C2776649630 @default.
- W2330346876 hasConcept C2777207669 @default.
- W2330346876 hasConcept C2777697162 @default.
- W2330346876 hasConcept C2778597550 @default.
- W2330346876 hasConcept C512968161 @default.
- W2330346876 hasConcept C75473681 @default.
- W2330346876 hasConceptScore W2330346876C119889771 @default.
- W2330346876 hasConceptScore W2330346876C126661725 @default.
- W2330346876 hasConceptScore W2330346876C155647269 @default.
- W2330346876 hasConceptScore W2330346876C161790260 @default.
- W2330346876 hasConceptScore W2330346876C178790620 @default.
- W2330346876 hasConceptScore W2330346876C179104552 @default.
- W2330346876 hasConceptScore W2330346876C185592680 @default.
- W2330346876 hasConceptScore W2330346876C2776164856 @default.
- W2330346876 hasConceptScore W2330346876C2776649630 @default.
- W2330346876 hasConceptScore W2330346876C2777207669 @default.
- W2330346876 hasConceptScore W2330346876C2777697162 @default.
- W2330346876 hasConceptScore W2330346876C2778597550 @default.
- W2330346876 hasConceptScore W2330346876C512968161 @default.
- W2330346876 hasConceptScore W2330346876C75473681 @default.
- W2330346876 hasIssue "7" @default.
- W2330346876 hasLocation W23303468761 @default.
- W2330346876 hasOpenAccess W2330346876 @default.
- W2330346876 hasPrimaryLocation W23303468761 @default.
- W2330346876 hasRelatedWork W1496687546 @default.
- W2330346876 hasRelatedWork W1975481134 @default.
- W2330346876 hasRelatedWork W2038544583 @default.
- W2330346876 hasRelatedWork W2050108200 @default.
- W2330346876 hasRelatedWork W2079700001 @default.
- W2330346876 hasRelatedWork W2282608620 @default.
- W2330346876 hasRelatedWork W2330346876 @default.
- W2330346876 hasRelatedWork W2353710418 @default.
- W2330346876 hasRelatedWork W2468697832 @default.
- W2330346876 hasRelatedWork W4232404062 @default.
- W2330346876 hasVolume "16" @default.
- W2330346876 isParatext "false" @default.
- W2330346876 isRetracted "false" @default.
- W2330346876 magId "2330346876" @default.
- W2330346876 workType "article" @default.