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- W2330352499 abstract "Isobaric vapor–liquid equilibria (VLE) for the binary systems ethanol + 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCA]) and water + [emim][DCA] as well as the VLE for the ternary system ethanol + water + [emim][DCA] have been obtained at 100 kPa using a recirculating still. The effect of [emim][DCA] on the ethanol + water system has been compared with that produced by another ionic liquid reported in the literature on the basis of the variation of solvent activity coefficients in ionic liquid (IL) + molecular solvent binary systems. From the results, [emim][DCA] appears as one of the best entrainers for the extractive distillation of the ethanol + water mixtures, causing the azeotrope to disappear at 100 kPa for ionic liquid mole fractions as low as 0.019. The experimental data were fitted with the Mock's electrolyte nonrandom two-liquid (NRTL) model, with a good agreement." @default.
- W2330352499 created "2016-06-24" @default.
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- W2330352499 date "2011-10-21" @default.
- W2330352499 modified "2023-09-23" @default.
- W2330352499 title "Isobaric Vapor–Liquid Equilibria for the Extractive Distillation of Ethanol + Water Mixtures Using 1-Ethyl-3-methylimidazolium Dicyanamide" @default.
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- W2330352499 doi "https://doi.org/10.1021/je200816z" @default.
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