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- W2330373036 abstract "We analyzed the vibrational frequencies of the Fe-bound carbon monoxide (CO) of myoglobin reconstituted with a series of chemically modified heme cofactors possessing a heme Fe atom with a variety of electron densities. The study revealed that the stretching frequency of Fe-bound CO (νCO) increases with decreasing electron density of the heme Fe atom (ρFe). This finding demonstrated that the νCO value can be used as a sensitive measure of the ρFe value and that the π back-donation of the heme Fe atom to CO is affected by the heme π-system perturbation induced through peripheral side chain modifications." @default.
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- W2330373036 date "2013-02-27" @default.
- W2330373036 modified "2023-09-23" @default.
- W2330373036 title "Relationship between the Electron Density of the Heme Fe Atom and the Vibrational Frequencies of the Fe-Bound Carbon Monoxide in Myoglobin" @default.
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- W2330373036 doi "https://doi.org/10.1021/ic3028447" @default.
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