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• W2330373920 abstract "A series of self-assembled monolayers (SAMs) on gold were generated by the adsorption of n-alkyl xanthic acids (NAXAs) having the general formula CH3(CH2)nOCS2H (n = 12–15). The structural features of these SAMs were characterized by optical ellipsometry, contact angle goniometry, polarization modulation infrared reflection absorption spectroscopy (PM-IRRAS), and X-ray photoelectron spectroscopy (XPS). This series of xanthate SAMs were compared to SAMs generated from the corresponding n-alkanethiols and aliphatic dithiocarboxylic acids (ADTCAs). The collected data indicate that the NAXAs generate densely packed and well-ordered monolayers. The contact angles of hexadecane on the xanthate monolayers exhibited a large “odd–even” effect similar to that produced by the ADTCA SAMs. The relative stability of these bidentate xanthate SAMs was evaluated by monitoring the changes in ellipsometric thicknesses and wettability as a function of time under various conditions. The results demonstrate that SAMs formed from NAXAs are much less stable than analogous n-alkanethiolate and ADTCA SAMs." @default.
• W2330373920 created "2016-06-24" @default.
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• W2330373920 date "2013-08-15" @default.
• W2330373920 modified "2023-10-16" @default.
• W2330373920 title "Synthesis, Characterization, and Relative Stabilities of Self-Assembled Monolayers on Gold Generated from Bidentate <i>n</i>-Alkyl Xanthic Acids" @default.
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• W2330373920 doi "https://doi.org/10.1021/la401098x" @default.
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