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- W2330376154 abstract "N-Silyl-aminotin trichlorides, R 1 R 2 N-SnCl 3 [R 1 = R 2 = SiMe 3 (1a), R 1 = SiMe 3 , R 2 = t Bu (1b), R = SiMe 3 , R 2 = 9-borabicyclo[3.3.1]nonyl (1c), R 1 R 2 = Me 2 SiCH 2 CH 2 SiMe 2 (1d)] were prepared by the reaction of tin tetrachloride with the respective bis(amino)plumbylenes, (R 1 R 2 N) 2 Pb 4. The analogous reactions with bis(amino)stannylenes, (R 1 R 2 N) 2 Sn 3, afforded only mixtures of the aminotin trichlorides 1 and bis(amino)tin dichlorides, (R 1 R 2 N) 2 SnCl 2 2 . The products were characterised by 1 H, 11 B, 13 C, 15 N, 29 Si and 119 Sn NMR spectroscopy, and the NMR data of 1 were compared with those of the corresponding N-silylamino(trimethyl)tin compounds 8." @default.
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- W2330376154 date "2001-10-01" @default.
- W2330376154 modified "2023-09-23" @default.
- W2330376154 title "N-Silylaminotin Trichlorides. Synthesis and Characterisation by Multinuclear Magnetic Resonance Spectroscopy" @default.
- W2330376154 doi "https://doi.org/10.1515/znb-2001-1008" @default.
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