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- W2330385003 abstract "By introduction of three differently structured rigid aromatic carboxylic acids as second organic ligands, three novel lead(II) carboxyphosphonates with 3D framework structures, namely, [Pb4(HL)(bts)2(H2O)]·2H2O (1), [Pb4(HL)(L)(bdc)1.5]·2H2O (2), and [Pb3(HL)2(Hssc)]·2H2O (3) (H3L = H2O3PCH2–NC5H9–COOH, NaH2bts = NaO3SC6H3(COOH)2, H2bdc = HOOCC6H4COOH, H3ssc = HOOCC6H3(SO3H)(OH)), have been synthesized under hydrothermal conditions and structurally characterized. The structure of compound 1 features a 3D network built by the cross-linking of 1D double chains of lead(II) phosphonates and 2D layers of lead(II) carboxylate-sulfonate. Compound 2 exhibits a 3D structure built up from PbII polyhedra, carboxyphosphonates, and bdc2– ions. The structure of compound 3 can be described as a 3D framework type. The Pb(1)O6, Pb(2)O4, Pb(3)O5, and CPO3 polyhedra are interconnected to form infinite double chain and the second linkers are hung in this chain, which is further connected to adjacent chains through carboxyphosphonate ligands to form a 3D framework structure. The luminescence properties of compounds 1–3 have also been studied." @default.
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- W2330385003 date "2011-09-15" @default.
- W2330385003 modified "2023-10-17" @default.
- W2330385003 title "Syntheses, Crystal Structures, and Luminescence Properties of Three Novel Lead Carboxyphosphonates with 3D Framework Structures Using Rigid Aromatic Carboxylic Acids as Second Organic Ligands" @default.
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- W2330385003 doi "https://doi.org/10.1021/cg200876t" @default.
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