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- W2330405907 startingPage "1854" @default.
- W2330405907 abstract "白金(Pt)および白金黒付白金(Pt-Pt)極を用い,ギ酸(IHCOOH),ホノレムアルデヒド(HCHO),メタノール(MeOH)のようなCl燃料のアノード酸化を行なうと反応中間体による電極の自己被毒が起こり電流値の低下が見られたが,Pb2+を添加するとPbのUnderPotentialDeposition(UPD)によって被毒作用がおさえられ,酸化電流に高揚が見られた。とくにHCOOHの場合にいちじるしい高揚が見られたが,HCHO,MeOHでもPb2÷濃度を増すと0.5～0.7VにHCOOHで見られるような酸化波があらわれ,PbによるUPD効果があることがわかった。しかしそれぞれのq化合物の酸化による反応中間体は異なると考えられ,HCOOHではCOHdが,MeOHではCOdが主として生成されると思われる。HCOOHの場合ににPbによる電極の被覆率と電流値高揚とよい相関関係が見られた。" @default.
- W2330405907 created "2016-06-24" @default.
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- W2330405907 date "1984-01-01" @default.
- W2330405907 modified "2023-10-16" @default.
- W2330405907 title "Enhancement of electrode catalysis by under potential deposition for anodic oxidation of C1 fuels." @default.
- W2330405907 doi "https://doi.org/10.1246/nikkashi.1984.1854" @default.
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