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• W2330551017 endingPage "1283" @default.
• W2330551017 startingPage "1272" @default.
• W2330551017 abstract "AbstractTwo multinuclear Co(II) complexes, [{Co(L)(i-PrOH)}2Co(H2O)]∙2CH3CN (1) and [{Co(L)(μ-OAc)Co(MeOH)2}2]∙2CH3COCH3 (2), have been synthesized with a new asymmetric Salamo-type ligand (H3L  =  6-hydroxy-6′-ethoxy-2,2′-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol). The Co(II) complexes were obtained by different solvents, and the structures are completely different. In the Co(II) complex 1, the ratio of the ligand H3L to Co(II) atom is 2 : 3 and the Co(II) ions are all five-coordinate with trigonal bipyramidal geometries. In the Co(II) complex 2, the ratio of the ligand H3L to Co(II) atom is 2 : 4. Two central Co(II) ions are six coordinate with distorted octahedral geometries and two terminal Co(II) ions are five coordinate with distorted trigonal bipyramidal geometries. Self-assembling of an infinite 1-D supramolecular chain is formed by C–H⋯π interactions in 1. Interestingly, an infinite 2-D-layer plane structure is formed by the self-assembling array of 2 linked by C–H⋯π interactions. 1 and ..." @default.
• W2330551017 created "2016-06-24" @default.
• W2330551017 creator A5010740832 @default.
• W2330551017 creator A5021816262 @default.
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• W2330551017 date "2016-04-02" @default.
• W2330551017 modified "2023-10-18" @default.
• W2330551017 title "Salamo-type trinuclear and tetranuclear cobalt(II) complexes based on a new asymmetry Salamo-type ligand: syntheses, crystal structures, and fluorescence properties" @default.
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• W2330551017 doi "https://doi.org/10.1080/00958972.2016.1168520" @default.
• W2330551017 hasPublicationYear "2016" @default.
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