Matches in SemOpenAlex for { <https://semopenalex.org/work/W2330578051> ?p ?o ?g. }
- W2330578051 endingPage "7194" @default.
- W2330578051 startingPage "7186" @default.
- W2330578051 abstract "The reaction of CO2 with Et3SiH catalyzed by the nickel complex [(dippe)Ni(μ-H)]2 (1) afforded the reduction products Et3SiOCH2OSiEt3 (12%), Et3SiOCH3 (3%), and CO, which were characterized by standard spectroscopic methods. Part of the generated CO was found as the complex [(dippe)Ni(CO)]2 (2), which was characterized by single-crystal X-ray diffraction. When the same reaction was carried out in the presence of a Lewis acid, such as Et3B, the hydrosilylation of CO2 efficiently proceeded to give the silyl formate (Et3SiOC(O)H) in high yields (85–89%), at 80 °C for 1 h. Further reactivity of the silyl formate to yield formic acid, formamides, and alkyl formates was also investigated." @default.
- W2330578051 created "2016-06-24" @default.
- W2330578051 creator A5047892519 @default.
- W2330578051 creator A5065768436 @default.
- W2330578051 creator A5086702064 @default.
- W2330578051 date "2013-11-04" @default.
- W2330578051 modified "2023-10-18" @default.
- W2330578051 title "Nickel-Catalyzed Hydrosilylation of CO<sub>2</sub> in the Presence of Et<sub>3</sub>B for the Synthesis of Formic Acid and Related Formates" @default.
- W2330578051 cites W1964885234 @default.
- W2330578051 cites W1970813681 @default.
- W2330578051 cites W1975506590 @default.
- W2330578051 cites W1988000325 @default.
- W2330578051 cites W1989005879 @default.
- W2330578051 cites W1995606776 @default.
- W2330578051 cites W1995664085 @default.
- W2330578051 cites W1999292430 @default.
- W2330578051 cites W2000321369 @default.
- W2330578051 cites W2001047002 @default.
- W2330578051 cites W2001341516 @default.
- W2330578051 cites W2003209532 @default.
- W2330578051 cites W2009413937 @default.
- W2330578051 cites W2013468066 @default.
- W2330578051 cites W2017267600 @default.
- W2330578051 cites W2032996018 @default.
- W2330578051 cites W2036657339 @default.
- W2330578051 cites W2037473344 @default.
- W2330578051 cites W2037946577 @default.
- W2330578051 cites W2041647217 @default.
- W2330578051 cites W2045445198 @default.
- W2330578051 cites W2047336609 @default.
- W2330578051 cites W2059020082 @default.
- W2330578051 cites W2063334178 @default.
- W2330578051 cites W2064045569 @default.
- W2330578051 cites W2065557321 @default.
- W2330578051 cites W2079036564 @default.
- W2330578051 cites W2091680897 @default.
- W2330578051 cites W2098395204 @default.
- W2330578051 cites W2100401647 @default.
- W2330578051 cites W2101687918 @default.
- W2330578051 cites W2103017255 @default.
- W2330578051 cites W2105512600 @default.
- W2330578051 cites W2105597435 @default.
- W2330578051 cites W2110659651 @default.
- W2330578051 cites W2113882249 @default.
- W2330578051 cites W2116346507 @default.
- W2330578051 cites W2126688530 @default.
- W2330578051 cites W2136653557 @default.
- W2330578051 cites W2145117406 @default.
- W2330578051 cites W2166825821 @default.
- W2330578051 cites W2315752527 @default.
- W2330578051 cites W2323300639 @default.
- W2330578051 cites W2332723755 @default.
- W2330578051 cites W2950031273 @default.
- W2330578051 cites W2950214969 @default.
- W2330578051 cites W2951231962 @default.
- W2330578051 cites W3138866156 @default.
- W2330578051 cites W4231121447 @default.
- W2330578051 doi "https://doi.org/10.1021/om400876j" @default.
- W2330578051 hasPublicationYear "2013" @default.
- W2330578051 type Work @default.
- W2330578051 sameAs 2330578051 @default.
- W2330578051 citedByCount "100" @default.
- W2330578051 countsByYear W23305780512014 @default.
- W2330578051 countsByYear W23305780512015 @default.
- W2330578051 countsByYear W23305780512016 @default.
- W2330578051 countsByYear W23305780512017 @default.
- W2330578051 countsByYear W23305780512018 @default.
- W2330578051 countsByYear W23305780512019 @default.
- W2330578051 countsByYear W23305780512020 @default.
- W2330578051 countsByYear W23305780512021 @default.
- W2330578051 countsByYear W23305780512022 @default.
- W2330578051 countsByYear W23305780512023 @default.
- W2330578051 crossrefType "journal-article" @default.
- W2330578051 hasAuthorship W2330578051A5047892519 @default.
- W2330578051 hasAuthorship W2330578051A5065768436 @default.
- W2330578051 hasAuthorship W2330578051A5086702064 @default.
- W2330578051 hasConcept C155647269 @default.
- W2330578051 hasConcept C161790260 @default.
- W2330578051 hasConcept C178790620 @default.
- W2330578051 hasConcept C179104552 @default.
- W2330578051 hasConcept C185592680 @default.
- W2330578051 hasConcept C2777379063 @default.
- W2330578051 hasConcept C2778421718 @default.
- W2330578051 hasConcept C504270822 @default.
- W2330578051 hasConceptScore W2330578051C155647269 @default.
- W2330578051 hasConceptScore W2330578051C161790260 @default.
- W2330578051 hasConceptScore W2330578051C178790620 @default.
- W2330578051 hasConceptScore W2330578051C179104552 @default.
- W2330578051 hasConceptScore W2330578051C185592680 @default.
- W2330578051 hasConceptScore W2330578051C2777379063 @default.
- W2330578051 hasConceptScore W2330578051C2778421718 @default.
- W2330578051 hasConceptScore W2330578051C504270822 @default.
- W2330578051 hasIssue "23" @default.
- W2330578051 hasLocation W23305780511 @default.
- W2330578051 hasOpenAccess W2330578051 @default.
- W2330578051 hasPrimaryLocation W23305780511 @default.
- W2330578051 hasRelatedWork W1501560638 @default.
- W2330578051 hasRelatedWork W2070457905 @default.