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- W2330588745 abstract "Random and block copolymerizations of poly(l-lactide) (PLLA) and poly(d-lactide) (PDLA) macromonomers having an exo-norbornene group at the α- or ω-chain end (D/L ratio = 1/1, Mn = ca. 5000 g mol–1) were performed via ring-opening metathesis polymerization to produce the brush random and block copolymers consisting of parallel or antiparallel aligned PLLA and PDLA side chains on a poly(norbornene) backbone. The molecular weight and polydispersity index of the brush copolymers were in the range of 40 300–458 000 g mol–1 and 1.03–1.14, respectively. Despite such high molecular weights, these brush copolymers formed a stereocomplex without homochiral crystallization. The melting temperature (Tm) and crystallinity (X) of the resulting stereocomplex varied depending on the backbone length, relative chain direction, and distribution of the PLLA/PDLA side chains. The parallel brush copolymers showed significantly higher Tm and X values than the antiparallel ones." @default.
- W2330588745 created "2016-06-24" @default.
- W2330588745 creator A5001507732 @default.
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- W2330588745 date "2014-10-16" @default.
- W2330588745 modified "2023-10-16" @default.
- W2330588745 title "Stereoblock-like Brush Copolymers Consisting of Poly(<scp>l</scp>-lactide) and Poly(<scp>d</scp>-lactide) Side Chains along Poly(norbornene) Backbone: Synthesis, Stereocomplex Formation, and Structure–Property Relationship" @default.
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- W2330588745 doi "https://doi.org/10.1021/ma501647m" @default.
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