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- W2330642802 abstract "Two reaction modes of homoannular double Friedel–Crafts acylation are realized using polyalkylphosphametallocenes as substrates. The first example is the reaction of tetra(tert-butyl)diphospharuthenocene with excess acetyl chloride/aluminum chloride, giving a 2,3-double Friedel–Crafts acylation product with an elimination of one of the tert-butyl groups. The other is the 2,5-diacylation of 1′,2′,3,3′,4,4′,5′-Me7-phosphaferrocene using an acyl chloride/aluminum chloride mixture. These reactions provide rare examples of doubly functionalized phosphametallocenes." @default.
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- W2330642802 date "2011-08-29" @default.
- W2330642802 modified "2023-09-23" @default.
- W2330642802 title "Homoannular Double Friedel–Crafts Acylation of Phosphametallocenes" @default.
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- W2330642802 doi "https://doi.org/10.1021/om200678q" @default.
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