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- W2330652590 abstract "By employing an N,N′-ditopic spacer 2-aminopyrazine (ampyz), two-dimensional (2D) (1) and three-dimensional (3D) (2) azido-bridged cobalt(II) coordination networks with the identical formula [Co(N3)2(ampyz)]n have been synthesized and characterized structurally and magnetically. Compound 1 was prepared by the layer diffusion method in ambient temperature and crystallized in the high symmetric space group Immm. The 2D square-grid structure of 1 contains the perfect symmetric linear of alternating double end-on (EO) and double end-to-end (EE) azido-bridged CoII chains which are linked together by an ampyz spacer in trans-arrangement. The intralayer π–π stacking interactions among ampyz spacers additionally stabilize this layer. The adjacent 2D layers are assembled by the intermolecular hydrogen bonding between the NH2 of the ampyz and the EE azido ligands building a 3D structure. Compound 2 was prepared by a hydrothermal technique and shows a 3D framework containing a zigzag chain of similarly alternating double EO and double EE azido-bridged CoII center. In contrast, this chain is linked by two ampyz spacers in cis-fashion giving rise to a 3D structure. The magnetic investigation of 1 shows the coexistence of a big spin canting angle and metamagnetism having magnetic ordering at 10 K, whereas the magnetic behavior of 2 simply exhibits spin-canted antiferromagnetism below TN of 16 K." @default.
- W2330652590 created "2016-06-24" @default.
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- W2330652590 date "2011-07-05" @default.
- W2330652590 modified "2023-10-18" @default.
- W2330652590 title "Spin Canting and Metamagnetism in 2D and 3D Cobalt(II) Coordination Networks with Alternating Double End-On and Double End-to-End Azido Bridges" @default.
- W2330652590 cites W1963567429 @default.
- W2330652590 cites W1966445935 @default.
- W2330652590 cites W1970878474 @default.
- W2330652590 cites W1971072621 @default.
- W2330652590 cites W1975360649 @default.
- W2330652590 cites W1976097044 @default.
- W2330652590 cites W1976229701 @default.
- W2330652590 cites W1980108663 @default.
- W2330652590 cites W1982439701 @default.
- W2330652590 cites W1985991470 @default.
- W2330652590 cites W1987440775 @default.
- W2330652590 cites W1988349811 @default.
- W2330652590 cites W1988949811 @default.
- W2330652590 cites W1990868190 @default.
- W2330652590 cites W1995351288 @default.
- W2330652590 cites W1995567294 @default.
- W2330652590 cites W1995631187 @default.
- W2330652590 cites W1999780610 @default.
- W2330652590 cites W2007338127 @default.
- W2330652590 cites W2007507293 @default.
- W2330652590 cites W2020848577 @default.
- W2330652590 cites W2021654467 @default.
- W2330652590 cites W2023328293 @default.
- W2330652590 cites W2025135711 @default.
- W2330652590 cites W2025773882 @default.
- W2330652590 cites W2029812407 @default.
- W2330652590 cites W2035653459 @default.
- W2330652590 cites W2037846035 @default.
- W2330652590 cites W2039401307 @default.
- W2330652590 cites W2043164916 @default.
- W2330652590 cites W2044205574 @default.
- W2330652590 cites W2050992886 @default.
- W2330652590 cites W2055070786 @default.
- W2330652590 cites W2055223466 @default.
- W2330652590 cites W2055554511 @default.
- W2330652590 cites W2055978952 @default.
- W2330652590 cites W2056175842 @default.
- W2330652590 cites W2060682046 @default.
- W2330652590 cites W2061945033 @default.
- W2330652590 cites W2064110899 @default.
- W2330652590 cites W2064546275 @default.
- W2330652590 cites W2068806383 @default.
- W2330652590 cites W2069828719 @default.
- W2330652590 cites W2070132142 @default.
- W2330652590 cites W2085157410 @default.
- W2330652590 cites W2086624247 @default.
- W2330652590 cites W2089879159 @default.
- W2330652590 cites W2091682326 @default.
- W2330652590 cites W2093411968 @default.
- W2330652590 cites W2095575229 @default.
- W2330652590 cites W2096450236 @default.
- W2330652590 cites W2096593854 @default.
- W2330652590 cites W2101605616 @default.
- W2330652590 cites W2116394532 @default.
- W2330652590 cites W2121332990 @default.
- W2330652590 cites W2131350133 @default.
- W2330652590 cites W2138301722 @default.
- W2330652590 cites W2147227480 @default.
- W2330652590 cites W2160774108 @default.
- W2330652590 cites W2165167119 @default.
- W2330652590 cites W2169349897 @default.
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- W2330652590 cites W4211133177 @default.
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- W2330652590 doi "https://doi.org/10.1021/ic201035c" @default.
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