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- W2330669519 endingPage "13125" @default.
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- W2330669519 abstract "1,3-[Ethylene-bis(aminocarbonylmethyl)]-p-tert-butylcalix[4]arene is analyzed and its optical properties are investigated, showing luminescence upon aggregation at low temperature or in the solid state described as aggregation-induced blue emission. The shift of the self-assembly from nanoporous to helical framework in the crystal is associated with a remarkable blue-shift and 33-fold increase in the fluorescence intensity. The purple-blue light emission is highly efficient (ΦF ∼ 60%) and is switched to thermally activated yellow emission as a stimuli-responsive behavior of the helical assembly. The emitting material has been characterized by single crystal and powder X-ray diffraction, ATR-FTIR spectroscopy, and DSC and PLTM analysis, and its optical properties are investigated." @default.
- W2330669519 created "2016-06-24" @default.
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- W2330669519 date "2014-06-09" @default.
- W2330669519 modified "2023-10-16" @default.
- W2330669519 title "Modulating the Self-Assembly of Calix[4]azacrowns to Design Materials with Improved Emission and Stimuli-Responsive Behavior" @default.
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- W2330669519 doi "https://doi.org/10.1021/jp5039392" @default.
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