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• W2330721212 abstract "Poly(3-hexylthiophene)-block-poly(3-(3-thioacetylpropyl) oxymethylthiophene) (P3HT)-b-(P3TT) diblock copolymers were synthesized and manipulated by solvent-induced crystallization to afford reversibly cross-linked semiconductor nanowires. To cross-link the nanowires, we deprotected the thioacetate groups to thiols and they subsequently oxidized to disulfides. Cross-linked nanowires maintained their structural integrity in solvents that normally dissolve the polymers. These robust nanowires could be reduced to the fully solvated polymer, representing a novel, reversible cross-linking procedure for functional P3HT-based nanowire fibrils. Field-effect transistor measurements were carried out to determine the charge transport properties of these nanostructures." @default.
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• W2330721212 date "2014-04-29" @default.
• W2330721212 modified "2023-10-14" @default.
• W2330721212 title "Reversible, Self Cross-Linking Nanowires from Thiol-Functionalized Polythiophene Diblock Copolymers" @default.
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• W2330721212 doi "https://doi.org/10.1021/am500976w" @default.
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