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• W2330790856 endingPage "10327" @default.
• W2330790856 startingPage "10319" @default.
• W2330790856 abstract "Reactions of laser-ablated, excited group 11 metal atoms with CH3F isotopomers have been carried out, leading to the generation of CH3–MF and CH2F–M complexes for Cu, Ag, and Au in addition to smaller complexes for gold. The products in the infrared spectra identified on the basis of their frequencies, isotopic shifts, and correlation with DFT calculated frequencies reveal that M–F insertion by the coinage metals and H atom release readily occur. The relatively low dissociation energies of CH3–AuF to give several smaller Au complexes are consistent with the observation of these fragments. The C–Au bonds of CF–AuH and CH2–AuF exhibit considerable π character, and the methylidene CH2–AuF contains a true double bond. In contrast, the bond orders of CH2–Au and CH2–AuH are lower, indicating that F bonded to Au contracts the gold 5d orbitals for better overlap with the carbon 2p orbital for π bonding." @default.
• W2330790856 created "2016-06-24" @default.
• W2330790856 creator A5029634322 @default.
• W2330790856 creator A5036641250 @default.
• W2330790856 date "2011-09-21" @default.
• W2330790856 modified "2023-10-18" @default.
• W2330790856 title "Infrared Spectra of CH₃–MF and Several Fragments Prepared by Methyl Fluoride Reactions with Laser-Ablated Cu, Ag, and Au Atoms" @default.
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• W2330790856 doi "https://doi.org/10.1021/ic2013842" @default.
• W2330790856 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21936488" @default.
• W2330790856 hasPublicationYear "2011" @default.
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