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- W2330802017 abstract "The synthesis of the new mixed amino–amido N-heterocyclic carbene 2, featuring a hypoxanthine structural unit, starting from caffeine via the hypoxanthinium precursor 4 is described. NHC 2 forms adducts with group 6 elements, coordinates to L2ClRh fragments (L2 = COD, (CO)2), or dimerizes to yield olefin 8. The donor properties of NHC 2 were evaluated by IR spectroscopic assessment of its TEP value (2058 cm–1), which is typical for an amino–amido NHC. Dicarbenes are also easily obtained by converting the imidazole moieties of the hypoxanthinium cation 4 or the olefin 8 into NHC functions. X-ray structure determinations of a Rh complex of carbene 2 and the olefinic dicarbene precursor 13 are presented." @default.
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- W2330802017 date "2012-10-10" @default.
- W2330802017 modified "2023-09-26" @default.
- W2330802017 title "Converting Caffeine to Electronically Different N-Heterocyclic Carbenes with a Hypoxanthine Backbone" @default.
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- W2330802017 doi "https://doi.org/10.1021/om300836w" @default.
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