Matches in SemOpenAlex for { <https://semopenalex.org/work/W2330802885> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W2330802885 endingPage "116" @default.
- W2330802885 startingPage "107" @default.
- W2330802885 abstract "The crystal structure of Na2S4O6 · 2H2O has been redetermined from three-dimensional X-ray intensity data and refined to R = 0.025 (Rw = 0.018) for 1620 observed reflections. The structure is monoclinic, space group C2, with a = 14.4726(5), b = 6.3716(3), c = 5.4402(3) Å, β = 105.53(1) °, Z = 2. Except for the chirality of the structure and the hydrogen positions, for which no information is given in the earlier work of Foss and Hordvik (1964), their structural model was confirmed by the present study. The tetrathionate anion possesses a two-fold symmetry axis. From the two independent S – S bonds of the anion the central bond is significantly shorter than the terminal one [2.019(1) Å versus 2.115(1) Å]. The S–S–S bond angle formed about the central S – S bond by the sulfur atoms is 89.55(2)°. The terminal SO3 groups of the anion have almost perfect trigonal symmetry [S–O: 1.447(1)–1.450(1) Å, O–S–O: 113.39(6)– 113.82(5)°]. The sodium cation is surrounded by six oxygen atoms in a distorted octahedral arrangement. [Na–O: 2.358(1)–2.465(1) Å]. By sharing opposite faces, columns of NaO6 octahedra are formed, which run parallel to b axis and are linked together through the sulfonate groups of the tetrathionate anions and through hydrogen bonds, in which the water molecules are involved. The chirality of the structure was determined with the Hamilton and the Bijvoet methods. Both indicated that the earlier structure proposal of Foss and Hordvik (1964) should be inversed for our crystal." @default.
- W2330802885 created "2016-06-24" @default.
- W2330802885 creator A5016662498 @default.
- W2330802885 creator A5030026838 @default.
- W2330802885 creator A5059301855 @default.
- W2330802885 date "1986-01-01" @default.
- W2330802885 modified "2023-09-27" @default.
- W2330802885 title "Crystal structure and chirality of sodium tetrathionate dihydrate, Na2S4O6· 2H2O" @default.
- W2330802885 cites W1970529966 @default.
- W2330802885 cites W1979364847 @default.
- W2330802885 cites W1982349236 @default.
- W2330802885 cites W1990105788 @default.
- W2330802885 cites W1990783771 @default.
- W2330802885 cites W2009148605 @default.
- W2330802885 cites W2030841140 @default.
- W2330802885 cites W2041327103 @default.
- W2330802885 cites W2043789384 @default.
- W2330802885 cites W2046047806 @default.
- W2330802885 cites W2049850818 @default.
- W2330802885 cites W2064081097 @default.
- W2330802885 cites W2071278571 @default.
- W2330802885 cites W2083932645 @default.
- W2330802885 cites W2136627217 @default.
- W2330802885 cites W2314021505 @default.
- W2330802885 cites W2326589246 @default.
- W2330802885 doi "https://doi.org/10.1524/zkri.1986.177.1-2.107" @default.
- W2330802885 hasPublicationYear "1986" @default.
- W2330802885 type Work @default.
- W2330802885 sameAs 2330802885 @default.
- W2330802885 citedByCount "4" @default.
- W2330802885 countsByYear W23308028852019 @default.
- W2330802885 crossrefType "journal-article" @default.
- W2330802885 hasAuthorship W2330802885A5016662498 @default.
- W2330802885 hasAuthorship W2330802885A5030026838 @default.
- W2330802885 hasAuthorship W2330802885A5059301855 @default.
- W2330802885 hasConcept C112887158 @default.
- W2330802885 hasConcept C115624301 @default.
- W2330802885 hasConcept C121332964 @default.
- W2330802885 hasConcept C124668440 @default.
- W2330802885 hasConcept C155860418 @default.
- W2330802885 hasConcept C178790620 @default.
- W2330802885 hasConcept C185592680 @default.
- W2330802885 hasConcept C198819137 @default.
- W2330802885 hasConcept C204795200 @default.
- W2330802885 hasConcept C20621625 @default.
- W2330802885 hasConcept C2776062316 @default.
- W2330802885 hasConcept C2781090017 @default.
- W2330802885 hasConcept C32909587 @default.
- W2330802885 hasConcept C518881349 @default.
- W2330802885 hasConcept C52703039 @default.
- W2330802885 hasConcept C61276311 @default.
- W2330802885 hasConcept C62520636 @default.
- W2330802885 hasConcept C71240020 @default.
- W2330802885 hasConcept C8010536 @default.
- W2330802885 hasConceptScore W2330802885C112887158 @default.
- W2330802885 hasConceptScore W2330802885C115624301 @default.
- W2330802885 hasConceptScore W2330802885C121332964 @default.
- W2330802885 hasConceptScore W2330802885C124668440 @default.
- W2330802885 hasConceptScore W2330802885C155860418 @default.
- W2330802885 hasConceptScore W2330802885C178790620 @default.
- W2330802885 hasConceptScore W2330802885C185592680 @default.
- W2330802885 hasConceptScore W2330802885C198819137 @default.
- W2330802885 hasConceptScore W2330802885C204795200 @default.
- W2330802885 hasConceptScore W2330802885C20621625 @default.
- W2330802885 hasConceptScore W2330802885C2776062316 @default.
- W2330802885 hasConceptScore W2330802885C2781090017 @default.
- W2330802885 hasConceptScore W2330802885C32909587 @default.
- W2330802885 hasConceptScore W2330802885C518881349 @default.
- W2330802885 hasConceptScore W2330802885C52703039 @default.
- W2330802885 hasConceptScore W2330802885C61276311 @default.
- W2330802885 hasConceptScore W2330802885C62520636 @default.
- W2330802885 hasConceptScore W2330802885C71240020 @default.
- W2330802885 hasConceptScore W2330802885C8010536 @default.
- W2330802885 hasIssue "1-2" @default.
- W2330802885 hasLocation W23308028851 @default.
- W2330802885 hasOpenAccess W2330802885 @default.
- W2330802885 hasPrimaryLocation W23308028851 @default.
- W2330802885 hasRelatedWork W2024690002 @default.
- W2330802885 hasRelatedWork W2024690656 @default.
- W2330802885 hasRelatedWork W2031538813 @default.
- W2330802885 hasRelatedWork W2040850106 @default.
- W2330802885 hasRelatedWork W2057760728 @default.
- W2330802885 hasRelatedWork W2067967944 @default.
- W2330802885 hasRelatedWork W2087080763 @default.
- W2330802885 hasRelatedWork W2097225352 @default.
- W2330802885 hasRelatedWork W646380683 @default.
- W2330802885 hasRelatedWork W2950420198 @default.
- W2330802885 hasVolume "177" @default.
- W2330802885 isParatext "false" @default.
- W2330802885 isRetracted "false" @default.
- W2330802885 magId "2330802885" @default.
- W2330802885 workType "article" @default.