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- W2330863695 abstract "Elemental silver was used as a reducing agent in the atom transfer radical polymerization (ATRP) of acrylates. Silver wire, in conjunction with a CuBr2/TPMA catalyst, enabled the controlled, rapid preparation of polyacrylates with dispersity values down to Đ = 1.03. The silver wire in these reactions was reused several times in sequential reactions without a decline in performance, and the amount of copper catalyst used was reduced to 10 ppm without a large decrease in control. A poly(n-butyl acrylate)-block-poly(tert-butyl acrylate) diblock copolymer was synthesized with a molecular weight of 91 400 and Đ = 1.04, demonstrating good retention of chain-end functionality and a high degree of livingness in this ATRP system." @default.
- W2330863695 created "2016-06-24" @default.
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- W2330863695 date "2015-01-27" @default.
- W2330863695 modified "2023-10-10" @default.
- W2330863695 title "A Silver Bullet: Elemental Silver as an Efficient Reducing Agent for Atom Transfer Radical Polymerization of Acrylates" @default.
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- W2330863695 doi "https://doi.org/10.1021/ja512519j" @default.
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