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• W2330890089 abstract "Polycrystalline samples of (CaxLa1-x)(Ba1.75-xLa0.25+x)Cu3O7+δ(CLBCO) tetragonal superconductor for x from 0.0 to 0.6 were studied by Raman scattering technique, which is sensitive to oxygen site symmetry in the high-Tc superconductors. On the Raman spectra, five extra modes at 200, 320, 400, 565 and 610 cm-1, which did not appear on Raman spectra of tetragonal YBa2Cu3O6, were observed. Based on the model that apical oxygen O(4) is displaced by La3+ on Ba site and the result of group theoretical analysis for this model, the 565 cm-1 mode which possessed the strongest intensity among these extra modes could be assigned to another O(4) vibration. This indicates that O(4) is strongly attracted by La3+ on Ba site, resulting in a change of local structure." @default.
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• W2330890089 date "2002-01-01" @default.
• W2330890089 modified "2023-09-24" @default.
• W2330890089 title "Observation of Local Crystal Structure Change in (CaxLa1-x)(Ba1.75-xLa0.25+x)Cu3O7+.DELTA. Tetragonal Superconductor Using Raman Scattering." @default.
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• W2330890089 doi "https://doi.org/10.2497/jjspm.49.372" @default.
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