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- W2330898851 abstract "The reactions of carbon monoxide under high pressure have been reviewed to show the results of some representative examples of kinetic and mechanism investigations performed in our laboratry.In the acid catalyzed reactions, three distinct patterns have been obtained, viz., the formation of carbonium cation by protonation with protonic acid, the intermediate formation of sultone-like structure by SO3, and the ion pair production of protonated cation with Lewis acid, all prior to CO addition.In the base catalyzed reactions, two kinds of patterns have been recognized so far, viz., the substrate and the base produce an active species which then reacts with CO, and the base combines with CO to form an active complex initially which then attacks the substrate." @default.
- W2330898851 created "2016-06-24" @default.
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- W2330898851 date "1978-01-01" @default.
- W2330898851 modified "2023-09-23" @default.
- W2330898851 title "Mechanism of carbon monoxide reactions under high pressure catalyzed by acids or bases." @default.
- W2330898851 cites W598594962 @default.
- W2330898851 doi "https://doi.org/10.1627/jpi1958.21.143" @default.
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