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- W2330929595 abstract "A possibility for hydrogen peroxide molecules to form stable complexes with atomic groups in the DNA backbone under the irradiation of the cell medium with high-energy ions has been studied. The energy of complexes is estimated, by taking the electrostatic and van der Waals interactions into account in the framework of the atom-atom potential function method. The interaction with metal counterions, which neutralize the surface charge of a macromolecule under natural conditions, is also taken into consideration. Stable configurations are determined for various complexes consisting of the atoms belonging to a DNA phosphate group, H2O2 and H2O molecules, and a Na+ metal ion. The complexes of hydrogen peroxide molecules with DNA phosphate groups and a counterion are shown to be not less stable than their complexes with water molecules. The attachment of an H2O2 molecule to a phosphate group of the double helix backbone can block the processes of DNA biological functioning and can deactivate the genetic mechanism of a cell." @default.
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- W2330929595 date "2016-04-01" @default.
- W2330929595 modified "2023-09-27" @default.
- W2330929595 title "Formation of Complexes of Hydrogen Peroxide Molecules with DNA" @default.
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- W2330929595 doi "https://doi.org/10.15407/ujpe61.03.0219" @default.
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