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- W2330950418 abstract "Abstract We have found that in the radical anions and nitroxides from p-alkylthionitrobenzenes, the alkylthiogroups behave as electron-withdrawing substituents and that their electron-acceptor character increases along the series methyl, ethyl, t-butyl. This behaviour could be explained in terms of a change of conformation of the SR substituent. Actually the ESR spectra of the radicals from the following isotopically substituted derivatives, show very different hyperfine splitting constants at the 13C: large and practically temperature independent in the case of the t-butylthionitrobenzene (II), and much smaller and strongly dependent on temperature with the methylthio analog (I). This finding provides evidence that in the latter derivative the methyl group deviates slightly from coplanarity with the aromatic ring, while the more stable conformation of (II) is that one placing the t-butyl group above the molecular plane with the Cp-S-13C plane perpendicular to the aromatic system." @default.
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- W2330950418 date "1979-03-01" @default.
- W2330950418 modified "2023-09-25" @default.
- W2330950418 title "CONFORMATIONAL DEPENDENCE OF THE ELECTRON ACCEPTOR CHARACTER OF ALKYLTHIOGROUPS IN ORGANIC RADICALS" @default.
- W2330950418 doi "https://doi.org/10.1080/03086647908080277" @default.
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