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- W2331093067 endingPage "1791" @default.
- W2331093067 startingPage "1787" @default.
- W2331093067 abstract "Oxidative coupling of arenes by dual C–H activation, thereby avoiding prefunctionalization of coupling partners, is the ideal way to synthesize biaryls. This letter reports a palladium-catalyzed regioselective oxidative arylation of furan-2-carbonyl compounds with simple arenes to 5-arylfuran-2-carbonyls. The key for the high regioselectivity is the use of F+ oxidants. The reaction is proposed to proceed through a Pd(II)–Pd(IV) catalytic cycle, wherein the substrates are activated by an electrophilic palladation mechanism, supported by preliminary mechanistic evidence." @default.
- W2331093067 created "2016-06-24" @default.
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- W2331093067 date "2012-07-23" @default.
- W2331093067 modified "2023-10-01" @default.
- W2331093067 title "Catalytic Regioselective Oxidative Coupling of Furan-2-Carbonyls with Simple Arenes" @default.
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- W2331093067 doi "https://doi.org/10.1021/cs300356y" @default.
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