Matches in SemOpenAlex for { <https://semopenalex.org/work/W2331130170> ?p ?o ?g. }
- W2331130170 endingPage "3372" @default.
- W2331130170 startingPage "3366" @default.
- W2331130170 abstract "The coupling reaction of N-propargyl semi-salen compound 1d on [Ru]-Cl ([Ru] = Cp(PPh3)2Ru) generates the carbene complex 3d containing a substituted 2H-chromene unit in 7 d. The precursor vinylidene complex 2d is isolated from the reaction of the propargyl group of 1d with [Ru]-Cl in 12 h. Addition of an o-cresol moiety to Cα and Cβ of the vinylidene ligand of 2d takes place in a longer reaction time to yield 3d. Reactions of [Ru]-Cl with other analogous compounds 1a, 1b, and 1c, in excess, also afford carbene complexes 3a, 3b, and 3c, respectively, in 48 h via a similar coupling process. Their precursor vinylidene complexes 2a, 2b, and 2c are also observed in 12 h. Structures of 2 and 3 are determined on the basis of spectroscopic data. The solid state structure of the dppe analogue 3a′ is further confirmed by X-ray diffraction analysis. The added o-cresol part comes from compounds 1, instead of aldehyde which is confirmed by the cross-coupling reactions of 2 and 1 using mass spectrometry. For comparison, treatment of [Ru]Cl with the amine analogue 13b retaining the propargyl and phenol moieties yields no coupling product." @default.
- W2331130170 created "2016-06-24" @default.
- W2331130170 creator A5001360388 @default.
- W2331130170 creator A5004931582 @default.
- W2331130170 creator A5012012554 @default.
- W2331130170 creator A5027336778 @default.
- W2331130170 date "2014-06-26" @default.
- W2331130170 modified "2023-10-16" @default.
- W2331130170 title "Coupling Reactions of <i>N</i>-Propargyl Semi-Salen Compounds Induced by Ruthenium Complex" @default.
- W2331130170 cites W147683373 @default.
- W2331130170 cites W1529457254 @default.
- W2331130170 cites W1554344691 @default.
- W2331130170 cites W1969784763 @default.
- W2331130170 cites W1971954391 @default.
- W2331130170 cites W1973007406 @default.
- W2331130170 cites W1979775657 @default.
- W2331130170 cites W1989183036 @default.
- W2331130170 cites W1991812639 @default.
- W2331130170 cites W1993132546 @default.
- W2331130170 cites W1999361566 @default.
- W2331130170 cites W1999748098 @default.
- W2331130170 cites W2005922832 @default.
- W2331130170 cites W2007193746 @default.
- W2331130170 cites W2011980702 @default.
- W2331130170 cites W2013158793 @default.
- W2331130170 cites W2021814953 @default.
- W2331130170 cites W2022305129 @default.
- W2331130170 cites W2027573694 @default.
- W2331130170 cites W2033641644 @default.
- W2331130170 cites W2034700369 @default.
- W2331130170 cites W2035232815 @default.
- W2331130170 cites W2039936602 @default.
- W2331130170 cites W2040718816 @default.
- W2331130170 cites W2043506029 @default.
- W2331130170 cites W2043752716 @default.
- W2331130170 cites W2044671462 @default.
- W2331130170 cites W2056858397 @default.
- W2331130170 cites W2061501449 @default.
- W2331130170 cites W2068940925 @default.
- W2331130170 cites W2072266835 @default.
- W2331130170 cites W2076115088 @default.
- W2331130170 cites W2076385429 @default.
- W2331130170 cites W2078725818 @default.
- W2331130170 cites W2080582136 @default.
- W2331130170 cites W2085290470 @default.
- W2331130170 cites W2085378370 @default.
- W2331130170 cites W2090258230 @default.
- W2331130170 cites W2094147979 @default.
- W2331130170 cites W2095531031 @default.
- W2331130170 cites W2097145118 @default.
- W2331130170 cites W2098727759 @default.
- W2331130170 cites W2110630328 @default.
- W2331130170 cites W2112274823 @default.
- W2331130170 cites W2120355202 @default.
- W2331130170 cites W2138482679 @default.
- W2331130170 cites W2144332006 @default.
- W2331130170 cites W2154828790 @default.
- W2331130170 cites W2162107320 @default.
- W2331130170 cites W2167699052 @default.
- W2331130170 cites W2317855805 @default.
- W2331130170 cites W2322474738 @default.
- W2331130170 cites W2326245324 @default.
- W2331130170 cites W2326985846 @default.
- W2331130170 cites W274377105 @default.
- W2331130170 cites W2950568692 @default.
- W2331130170 cites W2952116186 @default.
- W2331130170 cites W2952189082 @default.
- W2331130170 cites W3004514465 @default.
- W2331130170 doi "https://doi.org/10.1021/om500268x" @default.
- W2331130170 hasPublicationYear "2014" @default.
- W2331130170 type Work @default.
- W2331130170 sameAs 2331130170 @default.
- W2331130170 citedByCount "5" @default.
- W2331130170 countsByYear W23311301702014 @default.
- W2331130170 countsByYear W23311301702016 @default.
- W2331130170 countsByYear W23311301702021 @default.
- W2331130170 crossrefType "journal-article" @default.
- W2331130170 hasAuthorship W2331130170A5001360388 @default.
- W2331130170 hasAuthorship W2331130170A5004931582 @default.
- W2331130170 hasAuthorship W2331130170A5012012554 @default.
- W2331130170 hasAuthorship W2331130170A5027336778 @default.
- W2331130170 hasConcept C116569031 @default.
- W2331130170 hasConcept C131779359 @default.
- W2331130170 hasConcept C134121241 @default.
- W2331130170 hasConcept C155647269 @default.
- W2331130170 hasConcept C161790260 @default.
- W2331130170 hasConcept C170493617 @default.
- W2331130170 hasConcept C178790620 @default.
- W2331130170 hasConcept C185592680 @default.
- W2331130170 hasConcept C191897082 @default.
- W2331130170 hasConcept C192562407 @default.
- W2331130170 hasConcept C2776568683 @default.
- W2331130170 hasConcept C2777164566 @default.
- W2331130170 hasConcept C2777731188 @default.
- W2331130170 hasConcept C2779012754 @default.
- W2331130170 hasConcept C2779825165 @default.
- W2331130170 hasConcept C2780437523 @default.
- W2331130170 hasConcept C48424934 @default.