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- W2331187777 abstract "A series of well-dispersed carbon supported Pd catalysts were prepared by a simple and effective method under mild conditions. The functionalized carbon supported Pd catalyst (Pd/AC-H) demonstrated a enhanced performance to original carbon supported Pd catalyst (Pd/AC) in the probe reaction hydrogenation of 3,4-(1′,3′-Dibenzyl-2′-oxoimidazolido)-2-(4-carboxybutylidene)thiophane to dibenzylbiotinmethylester. The results of various characterization techniques revealed that the improvement of Pd dispersion on Pd/AC-H catalyst surface could be associated to the presence of abundant oxygen-containing groups available for anchorage. Furthermore, the role of the surface groups of carbon supports was indispensable since they could provide an efficient pathway for the reaction. The oxygen-containing groups located at the Pd-supports interface were able to adjust the strength of reactant adsorption/activation on the Pd active sites, which was responsible for the high yield of dibenzylbiotinmethylester." @default.
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- W2331187777 date "2016-05-01" @default.
- W2331187777 modified "2023-09-25" @default.
- W2331187777 title "Design and preparation of a simple and effective palladium catalyst and the hydrogenation performance toward dibenzylbiotinmethylester" @default.
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- W2331187777 doi "https://doi.org/10.1016/j.jcis.2016.01.066" @default.
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