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• W2331235104 abstract "A concise and simple synthetic approach to cis-syn-cis-triquinanes and -propellanes has been demonstrated via olefin metathesis starting with exo-nadic anhydride. This approach involves a ring-opening and ring-closing metathesis sequence of norbornene derivatives using Grubb's catalyst. Early-stage diallylation of norbornene derivatives is demonstrated followed by ring-closing metathesis that delivers propellanes exclusively. Surprisingly, ring-opening metathesis, late-stage diallylation, followed by ring-closing metathesis delivers triquinane as well as propellane derivatives." @default.
• W2331235104 created "2016-06-24" @default.
• W2331235104 creator A5014913253 @default.
• W2331235104 creator A5086926150 @default.
• W2331235104 date "2016-04-06" @default.
• W2331235104 modified "2023-10-16" @default.
• W2331235104 title "Target Specific Tactics in Olefin Metathesis: Synthetic Approach to <i>cis</i>-<i>syn</i>-<i>cis</i>-Triquinanes and -Propellanes" @default.
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• W2331235104 doi "https://doi.org/10.1021/acs.orglett.6b00537" @default.
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