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• W2331313748 endingPage "1697" @default.
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• W2331313748 abstract "Aromatic ynamines or N-alkynylheteroarenes are highly reactive alkyne components in Cu-catalyzed Huisgen [3 + 2] cycloaddition (“click”) reactions. This enhanced reactivity enables the chemoselective formation of 1,4-triazoles using the representative aromatic ynamine N-ethynylbenzimidazole in the presence of a competing aliphatic alkyne substrate. The unique chemoselectivity profile of N-ethynylbenzimidazole is further demonstrated by the sequential click ligation of a series of highly functionalized azides using a heterobifunctional diyne, dispelling the need for alkyne protecting groups." @default.
• W2331313748 created "2016-06-24" @default.
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• W2331313748 date "2016-03-22" @default.
• W2331313748 modified "2023-09-23" @default.
• W2331313748 title "Chemoselective Sequential Click Ligations Directed by Enhanced Reactivity of an Aromatic Ynamine" @default.
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• W2331313748 doi "https://doi.org/10.1021/acs.orglett.6b00635" @default.
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