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- W2331390329 abstract "Abstract Gold(I) complexes of overall formula LAuCl (L = various methylpyridines) are non-conducting in acetone. X-ray structure analyses show that the solid state structure of the cor responding complex 1 (L = 2-picoline) is molecular; the 3-picoline derivative 2 is however ionic (L 2 Au)+(AuCl 2 ) - . 3-Picoline forms a molecular complex LAuC 6 F 5 (3) and also the ionic (L 2 Au) + (SbF 6 ) - (4). Complexes 1, 2 and 4 display short Au ··· Au contacts, leading to chains of gold atoms; additionally, complexes 3 and 4 show weak Au ··· F contacts. The (3-picoline)-gold(III) complex trans-(L 2 AuCl 2 ) + (SbF 6 ) - (5) was obtained as a by-product; it too contains short Au ··· F contacts." @default.
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- W2331390329 date "1998-07-01" @default.
- W2331390329 modified "2023-09-26" @default.
- W2331390329 title "Gold(I)-Komplexe mit Aminliganden, II. (Methylpyridin)-Komplexe von Gold(I) Gold(I) / Complexes with Amine Ligands, II. Methylpyridine Complexes of Gold(I)" @default.
- W2331390329 doi "https://doi.org/10.1515/znb-1998-0702" @default.
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